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Как сделать ремонт квартиры собственными руками

как сделать ремонт квартиры собственными руками

как сделать ремонт квартиры собственными рукамиНапример, долгое время характерной функциональной атомной группировкой на ион Ti (1У). Считалась енортодиоловая ОН ОН - ОН ОН, имеющая место в полифенолах, полинафталях, взаимодействующих также с большой группой элементов ванадием, молибденом, железом, ниобием, танталом, цирконием, скандием и др. Многочисленные попытки изменить оставшуюся структуру молекулы реагента, кроме ХФАГА,. К успеху не приводили. При конструировании молекул реагентов с иной ХФАГА значительно изменились свойства реагента не только по селективности, но и по чувствительности. Переход от енортодиоловои к 1,3-диоловой и далее соответственно к оксимовой и 1-енол-3-оксимовой, а. Также 1-N, 3-енольной и l-N-4-енольной, реализующихся в гидроксаматах и диантипирилметанах позволили значительно повысить селективность реакций титана с реактивами, а в случае использования диантипирилметана получить специфический реактив. Таким образом, принимая во внимание возможность изменения ХФАГА, ее электронного строения, включающее изменение природы донорных атомов, объединенных молекулярными орбиталями, становится возможным за счет конструктивных элементов синтеза получать специфические реактивы или реактивы направленного действия на тот или иной элемент. Необходимость модификации ХФАГА может возникать на любом этапе конструирования реагента, его изучения и испытания даже в том случае, когда построение молекулы уже закончено, или на промежуточных этапах, когда среди возможных фрагментов и синтонов исследователь отбирает наиболее доступные.

 

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